Herein, we report the synthesis, characterization, and reactivity studies of a mononuclear manganese(IV)–oxo complex binding triflic acid, + ( 1–HOTf). However, such a binding of Lewis acids and proton at the metal–oxo group has been questioned in several cases and remains to be clarified. Performance, Health, and Well-being are Contagious.Binding of Lewis acidic metal ions and Brønsted acid at the metal–oxo group of high-valent metal–oxo complexes enhances their reactivities significantly in oxidation reactions. When a Stress Expert Battles Mental Illness. Redefining Success So It Doesn’t Crush Your Soul Nailing the Basics is Simple Not Easy-The Growth Equation Manifesto What is The Growth Equation-and Why You Should Pay Attention. But it should remind us that how we see the world is dependent on the skills and abilities we bring to the table. That doesn’t mean we should always listen to experts or default to those who have more experience in a field than we do. An expert who has developed multiple skill sets in his or her field sees the wall differently. But if we haven’t taken the time to develop deep skills and deep understanding, then we’ll surely miss a dozen holds and routes to the top that a seasoned veteran could pick out in a few seconds. This is akin to the false sense of security that googling a topic for an hour gives us. We might feel confident, assured that we’ve done the hard work inspecting the wall from top to bottom. We might think that we see the wall clearly because we’ve spent hours going over every bump and divot. In today’s climate, this principle is a reminder that how we perceive the world around us is dependent on our level of knowledge. You pick up on nuance when previously all you saw was one shade of grey. You start seeing the climbing wall, sentence, or field in a different light. Put differently: As your abilities change so does your perception. The NFL running back who gets the ball and sees three different lanes to run through versus the high school running back who sees no lane at all. The writer who takes a five-word sentence and sees dozens of variations while the high school student can’t see more than what is in front of her. You are the expert climber seeing two dozen routes to the top instead of only the obvious one. The greater your skill-set, the more possibilities you see. In the world of psychology, there’s a principle that states your skill-set determines your possibilities for action. We are staring at the same wall, but seeing very different things. He’d pick up small holds, places where he could wedge his hands, minor deviations on the surface of the wall that would give him enough friction, enough leverage, to get to the top. Now, if I took my good friend Andy who is an experienced climber and stuck him in front of the same wall, he’d see a completely different wall. I’d likely see only the obvious outcroppings, the holds upon which I could wrap my entire hand, knowing well that I was secure on the wall. I’d scan the wall, looking for places where I could grasp. If I were to try the sport of bouldering-climbing on small rock formations without a rope-I’d walk up to the rock wall and have no idea where to start.
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